Enantioselective synthesis of epoxides via Sharpless epoxidation of alkenylsilanols

TH Chan, LM Chen, D Wang…

Index: Chan, T. H.; Chen, L. M.; Wang, D.; Li, L. H. Canadian Journal of Chemistry, 1993 , vol. 71, # 1 p. 60 - 67

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Citation Number: 35

Abstract

AND D. WANG' AND L. H. LI Institute of Chernisrry, Acnclernia Sinicn, Beijing, People's Republic of Clzirzn TH CHAN, LM CHEN, D. WANG, and L. H. LI. Can. J. Chem. 71, 60 (1993). Enantioselective synthesis of simple epoxides can be achieved by Sharpless epoxidation of alkenylsilanols followed by protodesilylation of the chiral epoxysilanols. The approach has been applied to the synthesis of frontalin. ... T. H. CHAN, LM CHEN, D. WANG et LH Lr. Can. J. Chem. 71, 60 (1993). ...

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