Remarkably Robust Monomeric Alkylperoxyzinc Compounds from Tris (oxazolinyl) boratozinc Alkyls and O2

D Mukherjee, A Ellern, AD Sadow

Index: Mukherjee, Debabrata; Ellern, Arkady; Sadow, Aaron D. Journal of the American Chemical Society, 2012 , vol. 134, # 31 p. 13018 - 13026

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Citation Number: 24

Abstract

Metal alkylperoxides are remarkable, highly effective, yet often thermally unstable, oxidants that may react through a number of possible pathways including O–O homolytic cleavage, M– O homolytic cleavage, nucleophilic O-atom transfer, and electrophilic O-atom transfer. Here we describe a series of zinc alkyl compounds of the type ToMZnR (ToM= tris (4, 4-dimethyl-2- oxazolinyl) phenylborate; R= Et, n-C3H7, i-C3H7, t-Bu) that react with O2 at 25° C to form ...

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