A synthesis for β-aroylacrylic acids substituted with electron-withdrawing groups

L Steinbach, EI Becker

Index: Steinbach; Becker Journal of the American Chemical Society, 1954 , vol. 76, p. 5808

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Citation Number: 22

Abstract

Since the major product is the 1-isomer, it would be expected that the minor product, 11, would be the 3-isomer. Reduction of I1 with Raney nickel and low pressure hydrogen gave an amine melting at 195-200". It is interesting to note that hydrogen and platinum did not give clean results, though Raney nickel and hydrogen did. The amine appeared to be converted to a diazonium derivative in the usual manner, but neither pouring the ...

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