Redox Reactions of Amidato??Bridged cis??Diammineplatinum (III) Dinuclear Complexes with Phenol

…, H Fukushima, S Iwatsuki, K Ishihara…

Index: Hyodo, Shuntaro; Kishi, Masatoshi; Fukushima, Hiroyuki; Iwatsuki, Satoshi; Ishihara, Koji; Matsumoto, Kazuko European Journal of Inorganic Chemistry, 2012 , # 33 p. 5571 - 5577

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Abstract

Abstract Kinetic studies of the redox reactions of the head-to-tail (HT) α-pyridonato-bridged cis-diammineplatinum (III) dinuclear complex and of the head-to-head (HH) α-pyridonato- bridged and α-pyrrolidonato-bridged cis-diammineplatinum (III) dinuclear complexes with phenol were performed in acidic aqueous solution. Reduction of the HH Pt III dinuclear complexes with phenol proceeded only at pH> 3, whereas that of the HT Pt III dinuclear ...