Synthesis of Pt compounds containing chiral (2S, 4S)-pentane-2, 4-diyl-bis (5H-dibenzo [b] phosphindole) as ligand and their use in asymmetric hydroformylation of …
…, CJ Elsevier, JG de Vries, J Bakos, WJJ Smeets…
Index: Toth, Imre; Elsevier, Cornelis J.; De Vries, Johannes G.; Bakos, Jozsef; Smeets, Wilberth J. J.; Spek, Anthony L. Journal of Organometallic Chemistry, 1997 , vol. 540, # 1-2 p. 15 - 25
Full Text: HTML
Citation Number: 34
Abstract
Unlike bis (diphenyl) phosphine derivatives in general,(2S, 4S)-pentane-2, 4-diyl-bis (5H- dibenzo [b] phosphindole), S, S-BDBPP, gives a trans oligomeric compound [PtCl2 (S, S- BDBPP)] n, 1, in reaction with dichloro-Pt precursors such as PtCl2 (PhCN) 2, PtCl2 (CH3CN) 2 and PtCl2 (COD) at room temperature. Compound 1, which could be readily isolated, slowly rearranges in solutions at room temperature to the expected cis-monomer ...
Related Articles:
[Yan, Yongjun; Zhang, Xumu Journal of the American Chemical Society, 2006 , vol. 128, # 22 p. 7198 - 7202]
[Nozaki, Kyoko; Sakai, Nozomu; Nanno, Tetsuo; Higashijima, Takanori; Mano, Satoshi; Horiuchi, Toshihide; Takaya, Hidemasa Journal of the American Chemical Society, 1997 , vol. 119, # 19 p. 4413 - 4423]
[Parrinello, Giovanni; Stille, J. K. Journal of the American Chemical Society, 1987 , vol. 109, # 23 p. 7122 - 7127]
[Neibecker, Denis; Reau, Regis; Lecolier, Serge Journal of Organic Chemistry, 1989 , vol. 54, # 22 p. 5208 - 5210]
[Neibecker, Denis; Reau, Regis; Lecolier, Serge Journal of Organic Chemistry, 1989 , vol. 54, # 22 p. 5208 - 5210]