Mechanistic switch in dual gold catalysis of diynes: C (sp3)–H activation through bifurcation—vinylidene versus carbene pathways

…, M Rudolph, F Rominger, ASK Hashmi

Index: Hashmi, A. Stephen K.; Wieteck, Marcel; Braun, Ingo; Rudolph, Matthias; Rominger, Frank Angewandte Chemie - International Edition, 2012 , vol. 51, # 42 p. 10633 - 10637 Angew. Chem., 2012 , vol. 124, # 42 p. 10785 - 10789,5

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Citation Number: 112

Abstract

Transition-metal-catalyzed CÀH activation and functionalization is an area of broad interest as it enables the rapid creation of complex molecules in an atom-economic fashion.[1] The selective formation of CÀC bonds by means of CÀH activation of unactivated C (sp3) ÀH bonds without any directing groups in close proximity is still a challenging task in transition- metal catalysis and a highly active field of current research.[2] In the last decade gold ...

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