Water Encapsulation in a Polyoxapolyaza Macrobicyclic Compound

P Mateus, R Delgado, P Groves…

Index: Mateus, Pedro; Delgado, Rita; Groves, Patrick; Campos, Sara R. R.; Baptista, Antonio M.; Brandao, Paula; Felix, Vitor Journal of Organic Chemistry, 2012 , vol. 77, # 16 p. 6816 - 6824

Full Text: HTML

Citation Number: 5

Abstract

A new heteroditopic macrobicyclic compound (t2pN5O3) containing two separate polyoxa and polyaza compartments was synthesized in good yield through a [1+ 1]“tripod–tripod coupling” strategy. The X-ray crystal structure of H3t2pN5O33+ revealed the presence of one encapsulated water molecule accepting two hydrogen bonds from two protonated secondary amines and donating a hydrogen bond to one amino group. The acid–base ...

Related Articles:

Enantioselective synthesis of metathesis-derived ureapeptoid macrocycles

[Wang, Xiang-Zhu; Burke Jr., Terrence R. Synlett, 2004 , # 3 p. 469 - 472]

A simple and convenient manganese dioxide oxidation of benzyl halides to aromatic aldehydes under neutral condition

[Goswami, Shyamaprosad; Jana, Subrata; Dey, Swapan; Adak, Avijit Kumar Chemistry Letters, 2005 , vol. 34, # 2 p. 194 - 195]

A new route for the synthesis of ozagrel hydrochloride

[Yu, Chenglong; Zhao, Baohai; Zhao, Yihong; Lin, Jimao Organic Preparations and Procedures International, 2010 , vol. 42, # 2 p. 183 - 185]

Synthesis and evaluation of the antiparasitic activity of bis-(arylmethylidene) cycloalkanones

[Braga, Saulo F.P.; Alves, Erika V.P.; Ferreira, Rafaela S.; Fradico, Jordana R.B.; Lage, Paula S.; Duarte, Mariana C.; Ribeiro, Tatiana G.; Junior, Policarpo A.S.; Romanha, Alvaro J.; Tonini, Maiko L.; Steindel, Mario; Coelho, Eduardo F.; De Oliveira, Renata B. European Journal of Medicinal Chemistry, 2014 , vol. 71, p. 282 - 289]

Solid state nuclear bromination with N-bromosuccinimide. Part 2. Experimental and theoretical studies of reactions with some substituted benzaldehydes

[Sarma, Jagarlapudi A.R.P.; Nagaraju, Akula; Majumdar, Kanak K.; Samuel, Purnima M.; Das, Indira; Roy, Sujit; McGhie, Alistair J. Journal of the Chemical Society. Perkin Transactions 2, 2000 , # 6 p. 1119 - 1123]

More Articles...