A direct preparation of some pentafluorophenyl-containing silanes

A Whittingham, AWP Jarvie

Index: Whittingham, A.; Jarvie, A. W. P. Journal of Organometallic Chemistry, 1968 , vol. 13, p. 125 - 129

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Citation Number: 16

Abstract

Normally, using a Grignard or lithium synthesis, it is possible to substitute halo- and alkoxy-silanes with organic groups (R). Usually a mixture of variously substituted silanes is obtained and it appears that the Grignard synthesis of organo- halosilanes can be treated as a series of successive reactions of the type AX,+RY - AX,R,+rixy'. The lithium synthesis is considered to be very similar to that of the Grignard reaction, though the higher reactivity of the organolithium reagent, which ...