Chemistry letters

Ruthenium (II) Cl2-Bis (oxazolinyl) bipyridine Complex. Its Structure and Reactivity.

H Nishiyama, SB Park, M Haga, K Aoki, K Itoh

Index: Nishiyama, Hisao; Park, Soon-Bong; Haga, Masa-aki; Aoki, Katsuyuki; Itoh, Kenji Chemistry Letters, 1994 , # 6 p. 1111 - 1114

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Citation Number: 28

Abstract

A mixture of [Ru (II) Cl 2 (p-cymene)] 2 and 6, 6′-bis (oxazolinyl)-2, 2′-bipyridine (Bipymox- ip) was heated in ethanol at 70° C to produce Ru (II) Cl 2 (Bipymox-ip), of which structure was clarified by X-ray analysis to show that Bipymox-ip binds as a tetradentate ligand. Its catalytic activities for transformations of diazoacetates in dimerization and cyclopropanation with styrene were examined and its spectroelectrochemistry was studied.

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