Palladium supported on an acidic resin: a unique bifunctional catalyst for the continuous catalytic hydrogenation of organic compounds in supercritical carbon dioxide

T Seki, JD Grunwaldt, N van Vegten…

Index: Seki, Tsunetake; Grunwaldt, Jan-Dierk; Van Vegten, Niels; Baiker, Alfons Advanced Synthesis and Catalysis, 2008 , vol. 350, # 5 p. 691 - 705

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Citation Number: 44

Abstract

Abstract 1% Palladium-doped acidic resin (Amberlyst® 15; styrene-divinylbenzene matrix with sulfonic acid groups) is shown to be a highly active catalyst for the continuous catalytic hydrogenation of C [DOUBLE BOND] C bonds in supercritical carbon dioxide (scCO 2) without affecting C [DOUBLE BOND] O bonds. This 1% Pd/Amberlyst-15 catalyst promotes the industrially important selective formation of 2-ethylhexanal from crotonaldehyde in a “ ...

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