Stereochemistry of the Thermal Conversion of 1??Vinyl??2, 3??cis??dideuteriocyclobutane to Butadiene and 1, 2??Dideuterioethylenes

…, A Hutchinson, SJ Lever, EL Spaulding…

Index: Lewis, David K.; Hutchinson, Avery; Lever, Steven J.; Spaulding, Eric L.; Bonacorsi Jr., Samuel J.; Baldwin, John E. Israel Journal of Chemistry, 1996 , vol. 36, # 3 p. 233 - 237

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Citation Number: 9

Abstract

Abstract This study has examined the stereochemistry of the decomposition at 900–1000 K in a single-pulse shock tube of 1-vinyl-2, 3-cis-dideuteriocyclobutane to ethylenes and buta- 1, 3-dienes. The deuterated ethylenes formed during the decomposition, CHD [DOUBLE BOND] CH 2,(E)-CHD [DOUBLE BOND] CHD, and (Z)-CHD [DOUBLE BOND] CHD, were quantified via two independent techniques, FTIR and IR absorption spectroscopy using a ...

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