Synthesis of fluorinated derivatives of benzo [k] fluoranthene and indeno [1, 2, 3-cd] pyrene and 8, 9-dihydro-8, 9-epoxybenzo [k] fluoranthene

…, A Czech, N Hussain, EJ LaVoie

Index: Rice, Joseph E.; Czech, Anna; Hussain, Nalband; LaVoie, Edmond J. Journal of Organic Chemistry, 1988 , vol. 53, # 8 p. 1775 - 1779

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Citation Number: 15

Abstract

Difluoroindeno [1, 2, 3-~ d] pyrene was prepared from 1-(2-amino-4, 5-difluorophenyl) pyrene by diazotization followed by coupling in the presence of copper-bronze. In addition to these fluorinated derivatives, the synthesis of 8, 9-dihydro-8, 9-epoxybenzo [k] fluoranthene, a suspect ultimate tumorigenic metabolite of benzo [k] fluoranthene, is reported. This arene oxide was prepared from the trans-8, 9-bromo acetate by benzylic bromination and ...

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