The One??Pot Wittig Reaction: A Facile Synthesis of α, β??Unsaturated Esters and Nitriles by Using Nanocrystalline Magnesium Oxide

BM Choudary, K Mahendar, ML Kantam…

Index: Choudary, Boyapati M.; Mahendar, Koosam; Kantam, M. Lakshmi; Ranganath, Kalluri V. S.; Athar, Taimur Advanced Synthesis and Catalysis, 2006 , vol. 348, # 14 p. 1977 - 1985

Full Text: HTML

Citation Number: 55

Abstract

Abstract Nanocrystalline magnesium oxide was found to be an effective heterogeneous, solid base catalyst for the one-pot Wittig reaction to afford α, β-unsaturated esters and nitriles in excellent yields with high E-stereoselectivity in the presence of triphenylphosphine under mild conditions.

Related Articles:

Asymmetric synthesis of β-pyridyl-β-amino acid derivatives

[Bull, Steven D.; Davies, Stephen G.; Fox, David J.; Gianotti, Massimo; Kelly, Peter M.; Pierres, Camille; Savory, Edward D.; Smith, Andrew D. Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 16 p. 1858 - 1868]

Palladium??Catalyzed C??2 Selective C H Olefination of Pyridines

[Wen, Ping; Li, Yanmei; Zhou, Kang; Ma, Chao; Lan, Xiaobo; Ma, Chaowei; Huang, Guosheng Advanced Synthesis and Catalysis, 2012 , vol. 354, # 11-12 p. 2135 - 2140]

More Articles...