A Reformatsky Reagent. CC Bonds Formation by Substitution Reactions

F Orsini, F Pelizzoni

Index: Orsini, F.; Pelizzoni, F. Synthetic Communications, 1983 , vol. 13, # 6 p. 523 - 530

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Citation Number: 7

Abstract

... 523 Copyright 0 1983 by Marcel Dekker, Inc. 0039-791 1/83/1306-0523$3.50/0 Page 2. 524 ORSINI AND PELIZZONI The high regioselectivity displayed in the cou pling of t-butyl- l-bromocrotonate prompted us to test the ability of a C-metallated Reformatsky reagent to undergo nucleophilic substitutions with electrophiles ... bromoacetate and we have shmn that it is a C-metalla I f 2 BRZNCH2COOC ( C kj )ij - ted species with a Zn-C bond. ...