Chemistry Letters

Reactivity of. ALPHA.-metal (group 4) esters. Lewis acid mediated reactions of. ALPHA.-triphenyltin esters with aldehydes and acetals.

S Kiyooka, M Nakata

Index: Kiyooka, Syun-ichi; Nakata, Masumi Chemistry Letters, 1988 , p. 721 - 722

Full Text: HTML

Citation Number: 4

Abstract

Ethyl triphenylstannylacetate and ethyl α-triphenylstannylpropionate reacted with aldehydes and acetals to give β-hydroxy and β-alkoxy esters at room temperature in the presence of TiCl 4, in moderate yields. Under these conditions ethyl triphenylgermylacetate and ethyl trimethylsilylacetate did not work.

Related Articles:

A Practical Method for the Reformatsky Reaction of Aldehydes

[Chattopadhyay, Angshuman; Salaskar, Avinash Synthesis, 2000 , # 4 p. 561 - 564]

Titanocene (III)-promoted Reformatsky additions

[Parrish; Shelton, Daniel R.; Little, R. Daniel Organic Letters, 2003 , vol. 5, # 20 p. 3615 - 3617]

Titanocene (III)-promoted Reformatsky additions

[Parrish; Shelton, Daniel R.; Little, R. Daniel Organic Letters, 2003 , vol. 5, # 20 p. 3615 - 3617]

2, 2-Di (ethoxy) vinyllithium: Reactions with carbonyl compounds

[Hiouni, Abdelaziz; Duhamel, Lucette Tetrahedron Letters, 1996 , vol. 37, # 31 p. 5507 - 5510]

Uncatalyzed aldol reaction using a dimethylsilyl enolate and α-dimethylsilyl ester in N, N-dimethylformamide

[Miura, Katsukiyo; Sato, Hiroshi; Tamaki, Kentaro; Ito, Hajime; Hosomi, Akira Tetrahedron Letters, 1998 , vol. 39, # 17 p. 2585 - 2588]

More Articles...