Organothallium Compounds. XV. Thallation of Polyfluoroaromatic Compounds

GB Deacon, D Tunaley

Index: Deacon,G.B.; Tunaley,D. Australian Journal of Chemistry, 1979 , vol. 32, p. 737 - 753

Full Text: HTML

Citation Number: 17

Abstract

Abstract Thallic trifluoromethanesulfonate has been prepared by reaction of trifluoromethanesulfonic acid with either thallic oxide or solutions of thallic trifluoroacetate in trifluoroacetic acid, and has been isolated as the trihydrate on crystallization fromnitromethane. The polyfluoroarenes, p-CH 3 OC 6 F 4 H, p-CH 3 C 6 F 4 H, mH 2 C 6 F 4, oH 2 C 6 F 4, pH 2 C 6 F 4, C 6 F 5 H, 1, 3, 5-F 3 C 6 H 3 or 1, 2, 4-F 3 C 6 H 3, have ...