The Journal of Organic Chemistry

The chemistry of carbonyl chloride fluoride. I. The ring opening of cyclic ethers with carbonyl chloride fluoride

KO Christe, AE Pavlath

Index: Christe,K.O.; Pavlath,A.E. Journal of Organic Chemistry, 1965 , vol. 30, p. 1639 - 1643

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Citation Number: 4

Abstract

Ring opening of cyclic ethers by carbonyl chloride fluoride yielded w-chloroalkyl fluoroformates. The reactivity of carbonyl chloride fluoride with cyclic ethers was found to decrease in the order ethylene oxide> trimethylene oxide> tetrahydrofuran> tetrahydropyran. In addition, its reaction with substituted ethylene oxides and butadiene dioxide was investigated. The w-chloroalkyl fluoroformates, a new class of compounds, ...

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