New synthons for the synthesis of lanthanide containing macrocyclic schiff bases featuring substituents available for tethering
A Dumont, V Jacques, JF Desreux
Index: Dumont, Arnaud; Jacques, Vincent; Desreux, Jean F. Tetrahedron, 2000 , vol. 56, # 14 p. 2043 - 2052
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Citation Number: 21
Abstract
2, 6-Diacetylpyridine substituted with amine or alcohol groups in the 4-position have been prepared from chelidamic acid. The key 4-chloro derivative was synthesized in high yield via a diazo intermediate and was protected as a bis-1, 3-dioxane before substitution with various amino alcohol groups. Lanthanide macrocyclic tetra–imine complexes were obtained by a template procedure that leads to stable paramagnetic and/or fluorescent ...
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