Green Chemistry

Aerobic homocoupling of arylboronic acids catalysed by copper terephthalate metal–organic frameworks

P Puthiaraj, P Suresh, K Pitchumani

Index: Puthiaraj, Pillaiyar; Suresh, Palaniswamy; Pitchumani, Kasi Green Chemistry, 2014 , vol. 16, # 5 p. 2865 - 2875

Full Text: HTML

Citation Number: 27

Abstract

Copper terephthalate MOF is utilised as an environmentally benign, efficient and reusable heterogeneous catalyst to effect the aerobic homocoupling of arylboronic acids yielding the corresponding symmetrical biphenyls under mild reaction conditions. This method tolerates various substituents present in arylboronic acids such as halogens, cyano and nitro groups. The catalytic performance has been compared with that of other copper based MOFs ...

Related Articles:

Reactions of hypervalent iodine reagents with palladium: mechanisms and applications in organic synthesis

[Uchiyama, Masaharu; Suzuki, Takehiko; Yamazaki, Yasuo Chemistry Letters, 1983 , p. 1165 - 1166]

Copper (I)-catalysed homo-coupling of aryldiazonium salts: synthesis of symmetrical biaryls

[Cepanec, Ivica; Litvic, Mladen; Udikovic, Josipa; Pogorelic, Ivan; Lovric, Marija Tetrahedron, 2007 , vol. 63, # 25 p. 5614 - 5621]

The palladium-catalysed conjugate addition type reaction of arylmercury compounds with α, β-unsaturated ketones in a two-phase system

[Cacchi, S.; Misiti, D. Tetrahedron, 1981 , vol. 37, # 16 p. 2941 - 2946]

High-intensity ultrasound and microwave, alone or combined, promote Pd/C-catalyzed aryl–aryl couplings

[Cravotto, Giancarlo; Beggiato, Marina; Penoni, Andrea; Palmisano, Giovanni; Tollari, Stefano; Leveque, Jean-Marc; Bonrath, Werner Tetrahedron Letters, 2005 , vol. 46, # 13 p. 2267 - 2271]

Palladium-catalyzed reductive coupling of aromatic acid chlorides with disilanes

[Krafft, Terry E.; Rich, Jonathan D.; McDermott, Philip J. Journal of Organic Chemistry, 1990 , vol. 55, # 20 p. 5430 - 5432]

More Articles...