Trifluoromethanesulphonate esters and their alkylating properties
J Burdon, VCR McLoughlin
Index: Burdon, J.; McLoughlin, V. C. R. Tetrahedron, 1965 , vol. 21, p. 1 - 4
Full Text: HTML
Citation Number: 33
Abstract
CF3SOBF + C,H,O- + CF,SO&H, Instead, only diethyl ether was produced by 0-ethylation of the ethoxide ion: ... CF,S03C2H, + C,H50”' + (C,H&O + CF,S03- Ethyl trifluoromethanesulphonate must therefore ethytate ethoxide ion more rapidly than this ion reacts with the acid fluoride. The same authors* showed that methyl trifluoromethanesulphonate ... 0-alkylate diethyl ether to give methyl ethyl ether and that the ethyl ester reacted with benzene to give ethyl- and diethyl- ...
Related Articles:
[Velazquez, Carlos A.; Lynn, Geoffrey M.; Kumar, Vineet; Keefer, Larry K.; Malhotra, Sanjay V. Synthetic Communications, 2010 , vol. 40, # 9 p. 1322 - 1332]
[Ignat'ev, Nikolai V.; Barthen, Peter; Kucheryna, Andryi; Willner, Helge; Sartori, Peter Molecules, 2012 , vol. 17, # 5 p. 5319 - 5338]
[Ignat'ev, Nikolai V.; Barthen, Peter; Kucheryna, Andryi; Willner, Helge; Sartori, Peter Molecules, 2012 , vol. 17, # 5 p. 5319 - 5338]