1-Halosilatranes

MG Voronkov, VP Baryshok, LP Petukhov…

Index: Voronkov, M. G.; Baryshok, V. P.; Petukhov, L. P.; Rakhlin, V. I.; Mirskov, R. G.; Pestunovich, V. A. Journal of Organometallic Chemistry, 1988 , vol. 358, p. 39 - 56

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Citation Number: 48

Abstract

Abstract The electronic structure of 1-halosilatranes is discussed. Some new preparative methods based on hetero-and homo-lytic reactions of the silatrane and the Si-and C- substituted silatranes with halogenating reagents are described and also synthetic routes to 1-halosilatranes from certain organotrialkoxy-and organotrichlorosilanes. The electrophilic reactions of 1-iodosilatrane with ethers and esters, carbonyl compounds, alkoxysilanes ...