The Journal of Organic Chemistry

Bis (methoxycarbonyl) sulfur diimide, a convenient reagent for the allylic amination of alkenes

G Kresze, H Münsterer

Index: Kresze, G; Muensterer, H. Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3561 - 3564

Full Text: HTML

Citation Number: 53

Abstract

Notes conditions. 2 As a rule, these ene products spontaneously undergo a [2, 3]- sigmatropic rearrangement to afford N-(2-alkeny1) diamino sulfanes 3 (Scheme I). Particularly remarkable is the pronounced selectivity of product formation in these cases, as documented by many examples. From the results of our investigations3 the following conclusions can be drawn.(i) Whenever possible, the C= C bond of the diaminosulfanes 3 ...

Related Articles:

Alkyl and aryl isothiocyanates as masked primary amines

[Cho, Cheon-Gyu; Posner, Gary H. Tetrahedron Letters, 1992 , vol. 33, # 25 p. 3599 - 3602]

Synthesis and enzymic evaluation of conformationally defined carnitine analogs

[Brouillette, Wayne J.; Saeed, Ashraf; Abuelyaman, Ahmed; Hutchison, Tracy L.; Wolkowicz, Paul E.; McMillin, Jeanie B. Journal of Organic Chemistry, 1994 , vol. 59, # 15 p. 4297 - 4303]

Oximes: metabolic activation and structure− allergenic activity relationships

[Zaidlewicz, Marek; Uzarewicz, Ireneusz G. Polish Journal of Chemistry, 1988 , vol. 62, # 1-3 p. 143 - 150]

Oximes: metabolic activation and structure− allergenic activity relationships

[Zaidlewicz, Marek; Uzarewicz, Ireneusz G. Polish Journal of Chemistry, 1988 , vol. 62, # 1-3 p. 143 - 150]

Addition of Hydrogen Sulfide to Unsaturated Amines

[Turk,S.D. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 2846 - 2853]

More Articles...