The Preparation of Chlorides from Certain Aliphatic Branched Chain Secondary Carbinols1, 2

FC Whitmore, F Johnston

Index: Whitmore; Johnston Journal of the American Chemical Society, 1938 , vol. 60, p. 2267

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Citation Number: 15

Abstract

BY FRANK C. WHITMORE AND FRANKLIN JOHNSTON drogen chloride below 20'for ten weeks. The phosphorus trichloride gave only a phosphite. The other methods gave t-amyl chloride with only traces of material which might contain the secondary chloride. The low temp, erature treatment with hydrogen chloride repeatedly gave yields of over 90% of t-amyl chloride. This method was adopted as standard procedure with the other alcohols studied. ...