Journal of the American Chemical Society

Metathetical transposition of bis-tert-alkyl ketones. 1. A model for a study of group migration

JE Dubois, P Bauer

Index: Dubois,J.E.; Bauer,P. Journal of the American Chemical Society, 1976 , vol. 98, # 22 p. 6993 - 6999

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Citation Number: 5

Abstract

Abstract: Partial rate constants kpRm for the migration of alkyl groups are conventionally determined on the basis of approximations and hypotheses such that the set of values obtained is not necessarily consistent. The metathetical transposition of bistert-alkyl ketones constitutes a model reaction for which such assumptions are reduced to a minimum. A mechanistic study of this reaction shows a sequence of steps in common with two other ...

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