Journal of Organometallic Chemistry

Cumulated double bond systems as ligands: I. Dialkylsulfurdiimine compounds of platinum

J Kuyper, K Vrieze

Index: Kuyper,J.; Vrieze,K. Journal of Organometallic Chemistry, 1974 , vol. 74, p. 289 - 305

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Citation Number: 66

Abstract

Abstract The preparations and properties of a new series of compounds of the formula trans- [PtCl 2 (dialkylsulfurdiimine) L] are reported. In the case of the dimethyl-, diethyl-, diisopropyl- and dineopentyl-sulfurdiimine platinum compounds two isomers are present in solution, but only one isomer was observed for the di-t-butylsulfurdiimine derivative. 1 H and 13 C NMR data show that the two isomers interconvert intramolecularly by two different routes. In one ...