The Free Radical Addition of Hydrogen Bromide to the 1-Bromocycloalkenes1
PI Abell, C Chiao
Index: Abell,P.I.; Chiao,C. Journal of the American Chemical Society, 1960 , vol. 82, p. 3610 - 3613
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Citation Number: 23
Abstract
The addition of hydrogen bromide to 1-bromocyclobutene, 1-bromocyclopentene and 1- bromocycloheptene under free radical conditions gives ratios of cis to trans isomers of the 1, 2-dibromocycloalkanes of 79: 21, 94: 6 and 91: 9, respectively. These isomers have been separated and characterized. An explanation of the variation in isomer ratios is given in terms of a balance between a mechanistic preference for a trans addition process and a ...
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