Ruthenium??Catalyzed Propargylic Reduction of Propargylic Alcohols with Silanes

Y Nishibayashi, A Shinoda, Y Miyake…

Index: Nishibayashi, Yoshiaki; Shinoda, Akira; Miyake, Yoshihiro; Matsuzawa, Hiroshi; Sato, Mitsunobu Angewandte Chemie - International Edition, 2006 , vol. 45, # 29 p. 4835 - 4839

Full Text: HTML

Citation Number: 75

Abstract

A number of transition-metal complexes are known to promote the hydrosilylation of alkynes with silanes to give the corresponding vinyl silanes, which are versatile building blocks in organic synthesis.[1] The development of highly stereo-and regioselective hydrosilylation reactions of alkynes with silanes is an important subject in organic synthesis.[1] The selectivity in transition-metal-catalyzed hydrosilylation depends on the nature of catalysts, ...