The Journal of Organic Chemistry

Leaving group rate ratios in solvolytic displacement reactions. Effect of neighboring sulfur

DE Sunko, B Jursic, M Ladika

Index: Sunko, Dionis E.; Jursic, Branko; Ladika, Mladen Journal of Organic Chemistry, 1987 , vol. 52, # 11 p. 2299 - 2301

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Citation Number: 9

Abstract

One of intriguing problems in the study of solvolytic reactivity of organic substrates in nucleophilic substitution is the choice of proper rate ratios for various leaving groups.'Although some authors claim2y3 that leaving group effects in solvolytic reactions are not very sensitive to mechanistic changes, these effects often depend on various reaction characteristics such as a type of substrate,(1)(a) Lowry, TH; Richardson, KS Mechanism ...