Tetrahedron

Preparation and nucleophilic substitution of (E)-1-bromo-2-phenylsulfonyl-2-alkenes and 3-acetoxy-2-phenylsulfonyl-1-alkenes

P Auvray, P Knochel, JF Normant

Index: Auvray, P.; Knochel, P.; Normant, J. F. Tetrahedron, 1988 , vol. 44, # 19 p. 6095 - 6106

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Citation Number: 54

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Vinylphenylsulfone reacts with aldehydes to yield sulfonylated secondary allylic alcohols which are converted to either primary allylic bromides, or secondary allylic acetates. Both react highly regioselectively with lithium cyanocuprates, or enolates. ... Copyright © 1988 Pergamon ...