Tetrahedron letters

Total syntheses of (±)-crinine and (±)-buphanisine

SF Martin, CL Campbell

Index: Martin, Stephen F.; Campbell, Carlton L. Tetrahedron Letters, 1987 , vol. 28, # 5 p. 503 - 506

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Citation Number: 24

Abstract

Abstract. The concise total syntheses of the Amaryllidacea alkaloids (, t)-crinine (1) and (&- buphanisine (2) have been completed by a strategy that features the application of a general procedure for the elaboration of a quaternary carbon at a carbonyl center for construction of the key intermediate 4, 4-disubstituted cyclohexenone 7.