Spektroskopische Untersuchungen zu Substituenteneffekten in Silylmethylsilanen

E Popowski, U Marekowa, T Reiske…

Index: Popowski, E.; Marekowa, U.; Reiske, T.; Schulz, H.; Kelling, H. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1990 , vol. 583, p. 195 - 204

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Abstract

Abstract Die Silane Me 3− n (Me 3 SiCH 2) n SiH (n= 1–3),(RMe 2 SiCH 2) 3 SiH (R= n-Bu, n- Pr, Et, PhCH 2, Ph) und Me 3 ElCH 2 SiMe 2 H (El= Ge, Sn) wurden dargestellt. Die Bandenlagen der Si [BOND] H-Valenzschwingungen, die 29 Si [BOND] 1 H- Kopplungskonstanten und die 29 Si-NMR-chemischen Verschiebungen wurden gemessen. Die ṽ (SiH)-und J (29 Si [BOND] 1 H)-Werte der Silane Me 3− n (Me 3 SiCH 2) n SiH sind ...

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