Journal of organometallic chemistry

Low pressure pyrolysis of hexamethyldisilane: Electron spin resonance identification of radical intermediates

K Mach, GP Mills, JB Raynor

Index: Mach, Karel; Mills, Graham P.; Raynor, J. Barrie Journal of Organometallic Chemistry, 1997 , vol. 532, # 1-2 p. 229 - 233

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Citation Number: 4

Abstract

Radicals produced in the pyrolysis of hexamethyldisilane at pressures below 1.5 Torr have been trapped in an adamantane matrix at 77 K and characterised by electron spin resonance spectroscopy. At 1 Torr, results were consistent with mechanisms proposed from gas-phase kinetic studies. At lower pressures the results suggest surface decomposition predominates, and they reveal a surprising feature of the mechanism that would not have ...

Spektroskopische Untersuchungen zu Substituenteneffekten in Silylmethylsilanen

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A facile synthesis of tetrakis (trimethylsilyl) butatriene properties and cycloadditions

[Sakurai, Hideki; Kudo, Muneo; Sakamoto, Kenkichi; Nakadaira, Yasuhiro; Kira, Mitsuo; Sekiguchi, Akira Chemistry Letters, 1988 , # 8 p. 1441 - 1444]

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