Tetrahedron

Transformation of 1-(1, 2-propadienyl) cyclopropanols into substituted hydroquinones employing octacarbonyldicobalt

Y Owada, T Matsuo, N Iwasawa

Index: Owada, Yufu; Matsuo, Takeshi; Iwasawa, Nobuharu Tetrahedron, 1997 , vol. 53, # 32 p. 11069 - 11086

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Citation Number: 38

Abstract

A novel transformation of 1-(1, 2-propadienyl) cyclopropanols into substituted 1, 4- hydroquinones has been developed utilizing the interaction of 1, 2-propadienes and octacarbonyldicobalt (Co2 (CO) 8). This reaction was applied to the synthesis of vitamin E and K analogs.

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