Tetrahedron

Palladium-catalyzed desulfinylative C–C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters

CMR Volla, SR Dubbaka, P Vogel

Index: Rao Volla, Chandra M.; Dubbaka, Srinivas Reddy; Vogel, Pierre Tetrahedron, 2009 , vol. 65, # 2 p. 504 - 511

Full Text: HTML

Citation Number: 21

Abstract

2-Methylprop-2-ene-, prop-2-ene-, 1-methylprop-2-ene-, and (E)-but-2-enesulfonyl chlorides have been used as electrophilic partners in desulfinylative palladium-catalyzed C–C coupling with Grignard reagents and sodium salts of dimethyl malonate and methyl acetoacetate. Neopentyl alk-2-ene sulfonates can also be used as electrophilic partners in desulfinylative allylic arylations and allylic alkylations. The regioselectivity of the allylic ...

Related Articles:

Pd/P (t-Bu) 3: a mild and general catalyst for Stille reactions of aryl chlorides and aryl bromides

[Littke, Adam F.; Schwarz, Lothar; Fu, Gregory C. Journal of the American Chemical Society, 2002 , vol. 124, # 22 p. 6343 - 6348]

Palladium Nanoparticles in Glycerol: A Versatile Catalytic System for C X Bond Formation and Hydrogenation Processes

[Chahdoura, Faouzi; Pradel, Christian; Gomez, Montserrat Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3648 - 3660]

Phosphazene base-promoted halogen–zinc exchange reaction of aryl iodides using diethylzinc

[Ueno, Masahiro; Wheatley, Andrew E. H.; Kondo, Yoshinori Chemical Communications, 2006 , # 33 p. 3549 - 3550]

A highly effective (Triphenyl phosphite) palladium catalyst for a cross− coupling reaction of allylic alcohols with organoboronic acids

[Kayaki, Yoshihito; Koda, Takashi; Ikariya, Takao European Journal of Organic Chemistry, 2004 , # 24 p. 4989 - 4993]

Practical Iron??Catalyzed Allylations of Aryl Grignard Reagents

[Mayer, Matthias; Czaplik, Waldemar M.; Von Wangelin, Axel Jacobi Advanced Synthesis and Catalysis, 2010 , vol. 352, # 13 p. 2147 - 2152]

More Articles...