The Journal of organic chemistry

Radical Formation in the Oxidation of 2, 2'-Azo-2-methyl-6-heptene by Thianthrene Cation Radical

T Chen, HJ Shine

Index: Chen, Tonghua; Shine, Henry J. Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4716 - 4719

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Citation Number: 7

Abstract

Reaction of 2, 2'-azo-2-methyl-6-heptene (1) with thianthrene cation radical perchlorate (Th+ ClO4-) in CH2Cl2 solution containing 2, 6-di-tert-butyl-4-methylpyridine (DTBMP) gave a mixture of nine C8 hydrocarbons, namely, 1, 1, 2-trimethylcyclopentane (4, 2.2%), 6-methyl- 1-heptene (5, 2.2%), 2-methyl-1, 6-heptadiene (6, 9.8%), 2, 2-dimethyl-1- methylenecyclopentane (7, 2.9%), 6-methyl-1, 5-heptadiene (8, 39%), 3, 3-dimethyl-(9, 7.6 ...

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