Journal of Organometallic Chemistry

Organocuivreux vinyliques: IV. Etude de la regioselectivite de l'addition d'un alkylcuivre sur des alcynes β et γ fonctionnels

A Alexakis, J Normant, J Villieras

Index: Alexakis,A. et al. Journal of Organometallic Chemistry, 1975 , vol. 96, p. 471 - 485

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Citation Number: 37

Abstract

Abstract The syn addition of alkylcopper compounds to various alkynes HC C (CH 2) 2 Z (n= 2, 3, Z= X, NEt 2, SEt, OR) shows a regio-selectivity dependant on various factors, the major factors being the nature of the function and the solvent. The vinylcopper derivatives thus obtained have been carboxylated, iodinated and alkylated.

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