Kinetic study on the acid hydrolysis of 1??aryl??2??phenyl??2??imidazolines. Basicity??rate of hydrolysis and structure relationships
BM Fernández, AM Reverdito, IA Perillo…
Index: Fernandez, Beatriz M.; Reverdito, Ana M.; Perillo, Isabel A.; Lamdan, Samuel Journal of Heterocyclic Chemistry, 1983 , vol. 20, p. 1585 - 1588
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Abstract
Abstract Rate constants (k obs) of hydrolysis in sulfuric acid-water mixtures at 100 for five 1- aryl-2-phenyl-2-imidazolines were determined. The influence of substituents in the phenyl group at N-1 upon the rate of hydrolysis was studied. When the imidazoline ring is considered to be a substituent of the benzene ring at N-1, a good correlation with the Hammett equation is found.
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