The Journal of Organic Chemistry

Alkylation of the dianion of. beta.-keto sulfoxides. Versatile synthesis of phenyl (2-oxoalkyl) sulfoxides. General route to ketones, 1, 4-diketones, and aldols

PA Grieco, CS Pogonowski

Index: Grieco,P.A.; Pogonowski,C.S. Journal of Organic Chemistry, 1974 , vol. 39, # 5 p. 732 - 734

Full Text: HTML

Citation Number: 0

Abstract

... Syn., 46, 78 (1966)]. The nmr spectrum of phenyl (2-oxopropyl) sulfoxide has the fol- lowing signals: 6 (CC14) 2.23 (s, 3 H, COMe), 3.80 (s, 2 H, -CH2-), 7.55 (m, 5 H). One can prepare a- and y-substituted p-keto sulfoxides (eg, i) which provides for a general route to ketones (unpublished results, P. A. Grieco and CS Pogonowski). ... Department of Chemistry University of Pittsburgh Pittsburgh, Pennsylvania 15260 Paul A. Grieco* Chester S. Pogonowski ...

Related Articles:

Präparative Aspekte der aus β??Dicarbonylverbindungen synthetisierbaren 1, 3??Dithiolane

[Stahl, Ingfried; Schramm, Berthold; Manske, Rainer; Gosselck, Juergen Liebigs Annalen der Chemie, 1982 , # 6 p. 1158 - 1172]

Präparative Aspekte der aus β??Dicarbonylverbindungen synthetisierbaren 1, 3??Dithiolane

[Stahl, Ingfried; Schramm, Berthold; Manske, Rainer; Gosselck, Juergen Liebigs Annalen der Chemie, 1982 , # 6 p. 1158 - 1172]

Catalyst-controlled Wacker-type oxidation of homoallylic alcohols in the absence of protecting groups

[Stahl, Ingfried; Gosselck, Juergen Synthesis, 1980 , # 7 p. 561 - 563]

Über gezielte aldokondensationen—II

[Wittig,G.; Suchanek,P. Tetrahedron, Supplement, 1966 , vol. 8, p. 347 - 358]

Präparative Aspekte der aus β??Dicarbonylverbindungen synthetisierbaren 1, 3??Dithiolane

[Stahl, Ingfried; Schramm, Berthold; Manske, Rainer; Gosselck, Juergen Liebigs Annalen der Chemie, 1982 , # 6 p. 1158 - 1172]

More Articles...