Reactivity of Arenesulfinic Acids as Nucleophiles in the Addition Reaction to 2??Haloacrylonitriles

D Zvezdova, S Stoeva…

Index: Zvezdova; Stoeva; Aleksiev Journal of the Chinese Chemical Society, 2007 , vol. 54, # 2 p. 447 - 452

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Citation Number: 2

Abstract

Abstract The nucleophilic addition reactions of both the non-substituted and p-substituted benzenesulfinic acids with 2-chloro-and 2-bromoacrylonitriles have been studied. The structures of the 3-benzenesulfonyl-2-halogenopropanenitriles thus obtained were confirmed by microanalytical and spectral methods. The basic kinetic parameters of the reactions were determined and some local electronic descriptors concerning the reaction ...