Reductive aromatization of quinols. New convenient methods for the regiospecific synthesis of p-hydroxy C-aryl glycals

…, CA Coburn, PD Johnson, P Aristoff

Index: Parker, Kathlyn A.; Coburn, Craig A.; Johnson, Paul D.; Aristoff, Paul Journal of Organic Chemistry, 1992 , vol. 57, # 20 p. 5547 - 5550

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Citation Number: 37

Abstract

Among the naturally occurring C-aryl glycosides, the gilvocarcin antitumor antibiotics l2 are unique in that the carbohydrate substituent is positioned para to a phenolic hydroxyl group. Implicit in previous approaches to the establishment of this connection is the feasibility of liberating the phenolic hydroxyl group from a pakoxy C-aryl glycoside." For simple alkyl phenyl ethers, this dealkylation has not been demonstrated, and successful pre-partions ...

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