Metal promoted cyclization. 18. Novel cyclialkylation reactions of (. omega.-halo-1-alkenyl) metal derivatives. Synthetic scope and mechanism

E Negishi, LD Boardman, H Sawada…

Index: Negishi,E.; Boardman,L.D.; Sawada,H. Journal of the American Chemical Society, 1988 , vol. 110, p. 5383

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Citation Number: 87

Abstract

Conclusion. In general, solid-state five-coordinated tin structures lie along the Berry pseudorotational coordinate as an expression of their structural nonrigidity, similar to that found for other elements of groups 14 and 15 that have been studied. Implications are that in going down a particular family, nonrigid character

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