Tetrahedron

Optimization of a biocatalytic single-step alkene cleavage of aryl alkenes

H Mang, J Gross, M Lara, C Goessler, HE Schoemaker…

Index: Mang, Harald; Gross, Johannes; Lara, Miguel; Goessler, Christian; Schoemaker, Hans E.; Guebitz, Georg M.; Kroutil, Wolfgang Tetrahedron, 2007 , vol. 63, # 16 p. 3350 - 3354

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Citation Number: 22

Abstract

The oxidative cleavage of a CC double bond adjacent to an aryl moiety was achieved in the presence of a protein preparation of Trametes hirsuta G FCC 047 to yield the corresponding aldehydes. Molecular oxygen was the only oxidant required. All positive substrates had a CC bond conjugated to an aromatic system, all other compounds tested not fulfilling this requirement were non-substrates. The optimum reaction conditions are 20° C, pH 6–6.5, ...

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