The Journal of organic chemistry

Unexpected Catalyzed CC Bond Cleavage by Molecular Oxygen Promoted by a Thiyl Radical

X Baucherel, J Uziel, S Juge

Index: Maki, Shojiro; Niwa, Haruki; Hirano, Takashi Synlett, 1997 , # 12 p. 1385 - 1386

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Citation Number: 58

Abstract

... ie, p-ClPhS · ) favored this addition. 23c,d. On the other hand, since the β-hydroxysulfoxide 13 did not lead to the carbonyl products 6 and 7 (Scheme 3, eq 1), the carbon−carbon bond cleavage probably arises from the decomposition of the β-hydroperoxysulfide 12, catalyzed by ...

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