Neophyl-type Azo Compounds1; Their Decomposition and Rearrangement of the Neophyl-type Free Radical

CG Overberger, H Gainer

Index: Overberger; Gainer Journal of the American Chemical Society, 1958 , vol. 80, p. 4561,4564

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Citation Number: 10

Abstract

Neophyl radicals were generated by thermal decomposition in solution of azo compounds of the type [p-RC6H4C (CH3) 2-CH (CH,)-N= Iz where R= H, CH3O or CH&OSH. The rates of decomposition of the three compounds did not differ from each other by more than 31'%, from which it was concluded that the phenyl group did not participate appreciably in the dissociation of the carbon-nitrogen bond (the rate-determining step). The products ...