Novel type of transformations of α-azidostyrene derivatives and 3-aryl-2H-azirines in the presence of hexacarbonylmolybdenum

M Nitta, T Kobayashi

Index: Nitta, Makoto; Kobayashi, Tomoshige Chemistry Letters, 1983 , p. 1715 - 1718

Full Text: HTML

Citation Number: 18

Abstract

The reaction of α-azidostyrene derivatives with hexacarbonylmolybdenum was found to give 2, 5-diarylpyrroles and acetophenone derivatives via a complexed 1-arylvinylnitrene intermediate, while that of 3-aryl-2H-azirines gave 2, 4-diarylpyrroles in addition to acetophenone derivatives and 2, 5-diarylpyrazines.