Organic letters

Efficient and stereoselective synthesis of allylic ethers and alcohols

J Pospíšil, IE Markó

Index: Pospisil, Jiri; Marko, Istvan E. Organic Letters, 2006 , vol. 8, # 26 p. 5983 - 5986

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Citation Number: 30

Abstract

A short and efficient synthesis of allylic TBS ethers and allylic alcohols has been developed, based upon a unique Kocienski-Julia olefination reaction. Allylic alcohols and allylic ethers are obtained in good to excellent yields and with high (E)-selectivity. The conditions are mild and the procedure is broadly applicable.

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