Liebigs Annalen der Chemie

Partialsynthese des “Sargasterols” und des (20S)??Cholesterols

W Sucrow, MV Nooy

Index: Sucrow, Wolfgang; Nooy, Michael van Liebigs Annalen der Chemie, 1982 , # 10 p. 1897 - 1906

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Abstract

Abstract Die Eigenschaften des synthetischen (20S)-3β-Hydroxy-5-cholesten-24-ons (5b) und seines Acetats 5a unterscheiden sich signifikant von den für das Abbauprodukt des “Sargasterols” beschriebenen. Aus 5a, b wurden die E, Z-isomeren (20S)-Stigmasta-5, 24 (28)-dien-3β-ole 8b, 9b und ihre Acetate 8a, 9a sowie das (20S)-Cholesterol (10b) dargestellt.(20S)-Cholesterolacetat (10a) zeigt einen tieferen Schmelzpunkt als in der ...

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