Journal of organometallic chemistry

Isomerization of 1-alkenes using the Na 2 Fe (CO) 4/CuCl and Na 2 Fe (CO) 4/BrCH 2 CH 2 Br reagent systems

MR Reddy, M Periasamy

Index: Reddy, Malladi Rama; Periasamy, Mariappan Journal of Organometallic Chemistry, 1995 , vol. 491, # 1-2 p. 263 - 266

Full Text: HTML

Citation Number: 2

Abstract

The reagent Na2Fe (CO) 4 prepared in situ in THF by the reduction of Fe (CO) 5 with sodium naphthalenide reacts with certain alkenes in the presence of CuCl to bring about isomerization of the alkenes. Thus the 1-alkenes (1-dodecene, 1-decene, safrole and allyl benzene) are isomerized to trans-2-alkenes, and β-pinene is isomerized to α-pinene. Reactions involving BrCH2CH2Br in place of CuCl give similar results.

Related Articles:

Pd (O)-catalyzed electroreductive cleavage of allylic acetates

[Torii, Sigeru; Tanaka, Hideo; Katoh, Tetsuo; Morisaki, Kazuo Tetrahedron Letters, 1984 , vol. 25, # 30 p. 3207 - 3208]

Novel amphiphilic diphosphines: synthesis, rhodium complexes, use in hydroformylation and rhodium recycling

[Buhling, Armin; Elgersma, Jaap W.; Nkrumah, Steve; Kamer, Paul C. J.; Van Leeuwen, Piet W. N. M. Journal of the Chemical Society - Dalton Transactions, 1996 , # 10 p. 2143 - 2154]

Activations des reactifs de Grignard par les complexes du titane. Application du systeme “Cp2TiCl2—i-PrMgBr” comme agent reducteur

[Colomer,E.; Corrin,R. Journal of Organometallic Chemistry, 1974 , vol. 82, p. 367 - 373]

Oxidation of olefins by oxygen with a mixed palladium/silver nitrite catalyst in alcohols

[Sage, Jean-Marc; Gore, Jacques; Guilmet, Elisabeth Tetrahedron Letters, 1989 , vol. 30, # 46 p. 6319 - 6322]

Selectivity in the allylic substitutions with organometallics through neighboring coordination. 2-(Allyloxy) benzothiazoles as SN2'electrophiles for regio-and …

[Calo, Vincenzo; Lopez, Luigi; Pesce, Giannangelo; Calianno, Antonia Journal of Organic Chemistry, 1982 , vol. 47, # 23 p. 4482 - 4485]

More Articles...