The Journal of Organic Chemistry

Silicon-Promoted Carbon-Carbon Bond Formation between Ketones and Allyl-or Vinylsilanes Catalyzed by Manganese (IV) Dioxide

JR Hwu, BL Chen, SS Shiao

Index: Hwu, Jih Ru; Chen, Buh-Luen; Shiao, Shui-Sheng Journal of Organic Chemistry, 1995 , vol. 60, # 8 p. 2448 - 2455

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Citation Number: 23

Abstract

The electronic effect resulting from silicon can be used to control various types of organic reactions. Recent examples of silicon-promoted reactions include the Nef reaction'and ring contracti~ n;~~~ those of silicon-directed reactions include the aldol condensation: alkylative cy~ lization,~ Baeyer-Villiger~ xidation,~,~ Bamford-Stevens reaction, 8 Beckmann fragmentati~ n,~ carboncarbon bond cleavage, lOJ1 decarbonylation~,~~ J~ ...

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