The Journal of Organic Chemistry

Selective hydrosilylation of alkenes catalyzed by an organoyttrium complex

GA Molander, M Julius

Index: Molander, Gary A.; Julius, Manfred Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6347 - 6351

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Citation Number: 122

Abstract

Metal-catalyzed hydrosilylation procedures provide perhaps the most efficient and economical route to organosilanes, and a variety of catalysts have been developed for this reactions3 Curiously, relatively little effort has been made to develop general, synthetically useful procedures for hydrosilylation of polyolefins and functionalized alkene^.^ In this context we have found that (q5-C5Me5) 2YCH (SiMe3) 2 serves as an efficient and ...

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